Lives listing by occupation: politician
- Shaen, Sir James (died 1695), Irish politician, member of Parliament, civil servant, landowner, academician
- Sharman, Lieutenant-colonel — (flourished 1770–1790), Irish militia officer, politician
- Sharp, Richard (born 1759–died 1835), English politician, member of Parliament, wit, academician
- Shaw, Angus (died 1832), Canadian fur-trader, politician, tradesman
- Sheffield, John, 1st duke of Buckingham (born 1647–died 1721), English politician, poet
- Sherburne, Samuel (born 1757–died 1830), American lawyer, politician
- Sheridan, Charles Francis (born 1750–died 1806), Irish politician, member of Parliament, author
- Sheridan, Richard Brinsley (born 1751–died 1816), Irish author, playwright, politician
- Sheridan, Thomas (born 1775–died 1817), English theatre manager, politician
- Sherman, Roger (born 1721–died 1793), American merchant, politician
- Shute Barrington, John, 1st Viscount Barrington (born 1678–died 1734), English politician, speculator, author
- Shuvalov, Count Pyotr Ivanovich (born 1711–died 1762), Russian aristocrat, courtier, army officer, politician
- Sieyès, père Emmanuel Joseph, abbé Sieyès (born 1748–died 1836), French politician, revolutionary
- Silva Carvalho, José da (born 1782–died 1856), Portuguese politician
- Silvester, Peter (born 1734–died 1808), American politician
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