Lives listing by occupation: diplomat
- St John, Henry, 1st Viscount Bolingbroke (born 1678–died 1751), English politician, member of Parliament, diplomat, author
- Stolberg, Count Friedrich Leopold zu (born 1750–died 1819), Danish aristocrat, poet, translator, diplomat, religious convert, Catholic
- Sturz, Helfrich Peter (born 1736–died 1779), German diplomat, author
- Sullivan, John (born 1749–died 1839), Irish East India Company official, diplomat, politician, member of Parliament
- Sutton, Sir Robert (born 1672–died 1746), English diplomat, politician, member of Parliament
- Symonds, Samuel (born 1595–died 1678), American civil servant, colonial administrator, diplomat
- Talbot, Richard François, comte Tyrconnell (born 1710–died 1752), Scottish army officer, Jacobite, diplomat
- Talleyrand, Charles Maurice de (born 1754–died 1838), French churchman (lapsed), politician, diplomat
- Taulès, Pierre de, chevalier de Taulès (born 1731–died 1820), French civil servant, diplomat
- Temple, Sir John (born 1732–died 1798), American diplomat
- Temple, Sir William, baronet (born 1628–died 1699), English diplomat, politician, member of Parliament
- Tercier, Jean Pierre (born 1704–died 1767), French diplomat, academician, censor, civil servant, courtier
- Thévenot, Melchisédec (born c. 1620–died 1692), French author, scientist, inventor, cartographer, diplomat
- Thulemeier, Friedrich Wilhelm von (born 1735–died 1811), German government minister, diplomat
- Townshend, Charles, 2nd Viscount Townshend (born 1674–died 1738), English diplomat, agriculturalist
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