Lives listing by nationality: Spanish
- Silva y Álvarez de Toledo, Fernando de, duque de Alba (born 1714–died 1776), Spanish army officer, diplomat, patron
- Sociedad Patriotica de Amigos de la Cruz de Malta (active c. 1820), Spanish political body, revolutionary
- Solano y Bote Carrasco y Díaz, Don José de, marqués del Socorro (born 1726–died 1806), Spanish naval officer, colonial governor
- Somodevilla y Bengoechea, Zenón de, marqués de la Ensenada (born 1702–died 1781), Spanish aristocrat, statesman, civil servant, naval officer
- Spain, Cortes of (founded c. 1230), Spanish political body
- White, Joseph Blanco (born 1775–died 1841), Spanish churchman, editor, journalist, religious convert, Anglican
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